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Atoms, Elements and Compounds ยป Atoms, Elements and Compounds

What you'll learn this session

Study time: 30 minutes

AQA spec: 4.1.1.1

  • What atoms, elements and compounds are
  • How chemical symbols work, and the symbols you need to know
  • How to name a compound from its formula
  • How to write a word equation for a reaction

Everything is made of atoms

Everything on this table, from the phone to the salt to the plant, is built from atoms. Even the light-catching water!

Everything on this table, from the phone to the salt to the plant, is built from atoms. Even the light-catching water!

Look around you. Your phone, the air you breathe, the water in your glass and even you are all made of atoms. All substances are made of atoms. Atoms are far too small to see, even with an ordinary microscope, but they are the building blocks of everything.

An element is a substance made of only one type of atom. Gold is an element: a gold ring contains only gold atoms. Oxygen is an element too, and so is carbon. There are about 100 different elements, and every one of them is shown in the periodic table.

If you keep cutting a piece of gold into smaller and smaller bits, you eventually reach a single gold atom. You cannot go any smaller and still have gold. That is why the spec defines an atom like this: an atom is the smallest part of an element that can exist.

Key terms:

  • Atom: the smallest part of an element that can exist.
  • Element: a substance made of only one type of atom. There are about 100 of them, all shown in the periodic table.
  • Periodic table: the chart that shows every element, each with its own symbol.

Chemical symbols

Chemists all over the world use the same short code for each element. Each element's atoms are represented by a chemical symbol. For example, O represents an atom of oxygen and Na represents an atom of sodium.

✍ The capital letter rule

A symbol is one or two letters. The first letter is always a capital and the second letter is always small. So Co is cobalt, an element, but CO (two capitals) is carbon monoxide, a compound of carbon and oxygen. Writing a capital in the wrong place changes the meaning completely.

🏛 Odd-looking symbols

Some symbols don't match the English name because they come from old Latin names. Sodium is Na (from natrium), potassium is K (kalium), iron is Fe (ferrum), copper is Cu (cuprum), silver is Ag (argentum) and gold is Au (aurum). These are worth learning by heart.

You get a periodic table in the exam, but you must be able to use the names and symbols of the first 20 elements, the elements in Groups 1 and 7, and other elements in the specification. Here are the first 20:

  • H hydrogen, He helium, Li lithium, Be beryllium, B boron
  • C carbon, N nitrogen, O oxygen, F fluorine, Ne neon
  • Na sodium, Mg magnesium, Al aluminium, Si silicon, P phosphorus
  • S sulfur, Cl chlorine, Ar argon, K potassium, Ca calcium

Group 1 also includes rubidium (Rb), caesium (Cs) and francium (Fr). Group 7 also includes bromine (Br), iodine (I) and astatine (At). Notice the UK spellings the exam uses: aluminium, sulfur and caesium.

Compounds

A compound contains two or more elements chemically combined in fixed proportions. Water is a compound of hydrogen and oxygen. Table salt (sodium chloride) is a compound of sodium and chlorine.

Compounds are formed from elements by chemical reactions. A chemical reaction always makes one or more new substances, and it often involves a detectable energy change, such as the mixture getting hot, giving out light or getting cold.

⚗ New substance

A compound can be totally different from its elements. Sodium is a soft, very reactive metal and chlorine is a poisonous green gas, yet sodium chloride is the salt you sprinkle on chips.

⚖ Fixed proportions

Water is always H2O: two hydrogen atoms for every one oxygen atom. Water from a tap, a river or a cloud always has this exact ratio.

🔓 Hard to split

Compounds can only be separated into their elements by chemical reactions. Boiling water just gives steam, which is still water.

A compound is shown by a formula made from the symbols of the atoms it was formed from. The small number after a symbol tells you how many of that atom there are. If there is no number, there is one.

  • CO2 means 1 carbon atom and 2 oxygen atoms.
  • NH3 means 1 nitrogen atom and 3 hydrogen atoms.
  • CaCO3 means 1 calcium, 1 carbon and 3 oxygen atoms.

Key terms:

  • Compound: two or more elements chemically combined in fixed proportions.
  • Chemical reaction: a change that forms one or more new substances, often with a detectable energy change.
  • Formula: symbols (and numbers) that show which atoms are in a compound and in what ratio.

Some substances are just elements or compounds mixed together without being chemically joined. You will meet these in a later lesson, Mixtures and Separation Techniques.

Naming compounds from formulae

You need to be able to name a compound when you are given its formula. A few simple rules do most of the work.

  • Metal first: the metal keeps its normal name. NaCl starts with sodium.
  • Two elements only, ending in -ide: the non-metal changes its ending. Chlorine becomes chloride, oxygen becomes oxide, sulfur becomes sulfide, bromine becomes bromide. So NaCl is sodium chloride and MgO is magnesium oxide.
  • Oxygen as well, often -ate: CO3 is carbonate, SO4 is sulfate and NO3 is nitrate. So CaCO3 is calcium carbonate and CuSO4 is copper sulfate.
  • OH is hydroxide: NaOH is sodium hydroxide.

Some compounds just have names you need to know. H2O is water, CO2 is carbon dioxide ("di" means two) and NH3 is ammonia.

Worked example: naming compounds

KBr: K is potassium, a metal, so it goes first. Br is bromine, and there are only two elements, so it becomes bromide. Answer: potassium bromide.

Li2O: Li is lithium. O is oxygen, the only other element, so it becomes oxide. Answer: lithium oxide. (The 2 tells you there are two lithium atoms, but it doesn't change the name.)

MgSO4: Mg is magnesium. SO4 is sulfate. Answer: magnesium sulfate.

Word equations

Those fizzing bubbles are hydrogen gas: magnesium + hydrochloric acid โ†’ magnesium chloride + hydrogen

Those fizzing bubbles are hydrogen gas: magnesium + hydrochloric acid โ†’ magnesium chloride + hydrogen

Chemical reactions can be shown by word equations or by equations using symbols and formulae. A word equation is the simplest kind. It uses only names.

  • Reactants are the substances you start with. They go on the left.
  • Products are the new substances made. They go on the right.
  • An arrow points from reactants to products. It means "react to make".
  • A plus sign separates two reactants or two products.

When iron is heated with sulfur, the two elements react to make a new compound:

iron + sulfur → iron sulfide

You can also go the other way: given a symbol equation, you should be able to write it in words. For example:

2H2 + O2 → 2H2O becomes hydrogen + oxygen → water

The big numbers in front are for balancing, which you will learn in the next lesson, Writing Formulae and Balanced Equations. They never appear in a word equation.

Common mistakes

Using "=" instead of an arrow. A reaction is a change, not a sum. Always use →.

Calling a compound "chlorine" or "oxygen". Once an element is combined, its name changes, so it is sodium chloride, not sodium chlorine.

Wrong capitals. CO and Co are different substances. So are NaCL and NaCl, and only NaCl is correct.

Mixing up -ide and -ate. Copper sulfide (CuS) contains no oxygen. Copper sulfate (CuSO4) does.

Exam-style question

Calcium reacts with chlorine to make calcium chloride, CaCl2.

(a) Give the symbol for calcium. [1 mark]

(b) Write a word equation for this reaction. [1 mark]

(c) Calcium chloride is a compound. Explain what is meant by a compound. [2 marks]

Model answer

(a) Ca

(b) calcium + chlorine → calcium chloride

(c) A substance containing two or more elements (1) chemically combined in fixed proportions (1).

Exam tip

When you write a symbol, check the capital letters before you move on. Ca is calcium, but CA or ca would lose the mark.

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