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pH and Salinity » Carbon Dioxide Effects on Seawater pH

What you'll learn this session

Study time: 30 minutes

  • How carbon dioxide dissolves in seawater and forms carbonic acid
  • The relationship between CO₂ levels and ocean pH changes
  • What ocean acidification means and why it matters
  • How marine organisms are affected by changing pH levels
  • Real-world examples of pH changes in different ocean regions
  • Methods scientists use to measure and monitor ocean pH

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Introduction to Carbon Dioxide Effects on Seawater pH

Our oceans are like giant sponges that soak up carbon dioxide from the atmosphere. When CO₂ dissolves in seawater, it creates a chemical reaction that makes the water more acidic. This process is happening right now in oceans around the world and it's having major effects on marine life.

Understanding how carbon dioxide affects seawater pH is crucial for marine science because it helps us predict what will happen to ocean ecosystems as atmospheric CO₂ levels continue to rise.

Key Definitions:

  • pH: A scale from 0-14 that measures how acidic or basic a solution is. Lower numbers mean more acidic.
  • Ocean Acidification: The ongoing decrease in ocean pH caused by absorption of atmospheric carbon dioxide.
  • Carbonic Acid: A weak acid formed when CO₂ dissolves in water (H₂CO₃).
  • Saturation State: How easily marine organisms can build shells and skeletons from calcium carbonate.

🌊 The Ocean's pH Scale

Seawater is naturally slightly basic with a pH around 8.1. When we say oceans are becoming more "acidic," we mean the pH is dropping towards neutral (7.0). Even small changes in pH represent huge changes in acidity because the pH scale is logarithmic - a drop of 0.1 pH units means a 26% increase in acidity!

How Carbon Dioxide Dissolves in Seawater

When carbon dioxide from the atmosphere meets the ocean surface, it doesn't just sit there - it gets busy creating a whole chain of chemical reactions that change the water's chemistry.

The Chemical Process

Here's what happens step by step when CO₂ enters seawater:

CO₂ Dissolves

Carbon dioxide gas dissolves directly into the seawater at the surface, just like fizzy drink bubbles dissolving in water.

Carbonic Acid Forms

The dissolved CO₂ reacts with water molecules to form carbonic acid (H₂CO₃), which is unstable and quickly breaks down.

Ions Released

Carbonic acid releases hydrogen ions (H⁺) and bicarbonate ions (HCO₃⁻), making the water more acidic.

The more CO₂ that dissolves, the more hydrogen ions are released and the lower the pH becomes. This is why rising atmospheric CO₂ levels directly lead to more acidic oceans.

Amazing Ocean Fact

The oceans absorb about 25% of all the CO₂ that humans put into the atmosphere each year. That's roughly 22 million tonnes of CO₂ every single day! Without this ocean absorption, atmospheric CO₂ levels would be much higher than they are now.

Measuring Ocean pH Changes

Scientists have been tracking ocean pH for decades and the results show clear patterns of acidification happening worldwide.

Historical pH Trends

Since the Industrial Revolution began around 1750, ocean pH has dropped by about 0.1 units globally. This might sound small, but remember - it represents a 26% increase in acidity across all the world's oceans.

📈 Before 1750

Ocean pH was stable at around 8.2 for thousands of years. Marine ecosystems evolved and adapted to these consistent chemical conditions.

📉 Today

Average ocean pH is now around 8.1 and continuing to drop. The rate of change is faster than anything seen in the geological record for millions of years.

Regional Variations in pH

Not all parts of the ocean are experiencing the same pH changes. Some regions are becoming acidic faster than others due to local conditions.

Arctic Waters

The Arctic Ocean is experiencing some of the most rapid acidification on Earth. Cold water absorbs more CO₂ than warm water and melting ice is adding fresh water that has different chemical properties.

Case Study: Bering Sea

In Alaska's Bering Sea, pH levels have dropped so much that some areas now have water that's corrosive to shell-building organisms. Crab fishermen have reported finding crabs with damaged shells and some fish populations are showing signs of stress from the changing water chemistry.

Coastal Upwelling Zones

Areas where deep, CO₂-rich water rises to the surface (like off the coasts of California and Peru) are experiencing particularly severe acidification. These waters were already more acidic and additional CO₂ is pushing them to extreme levels.

Effects on Marine Life

Changing ocean pH doesn't just affect water chemistry - it has direct impacts on the creatures that call the ocean home.

Shell and Skeleton Building

Many marine animals build their shells and skeletons from calcium carbonate, which becomes harder to form as water becomes more acidic.

🦀 Shellfish

Oysters, mussels and clams struggle to build strong shells in acidic water. Young shellfish are especially vulnerable during their early development.

🐟 Coral Reefs

Corals find it harder to build their calcium carbonate skeletons, leading to weaker reef structures that are more easily damaged by storms.

🦔 Sea Urchins

These spiny creatures have trouble forming their protective shells, making them more vulnerable to predators and environmental stress.

Fish Behaviour Changes

Even fish without shells are affected by changing pH. Acidic water can interfere with their nervous systems, affecting their ability to smell, navigate and avoid predators.

Case Study: Clownfish and Anemones

Research on the Great Barrier Reef has shown that clownfish raised in more acidic water lose their ability to recognise the smell of their home anemone. This makes it much harder for young fish to find safe places to live, potentially disrupting entire reef communities.

Monitoring and Research Methods

Scientists use various tools and techniques to track ocean pH changes and understand their effects.

pH Measurement Techniques

Modern oceanographers use sophisticated equipment to measure pH with incredible precision.

🚢 Research Vessels

Ships equipped with automated pH sensors travel regular routes, collecting continuous data about ocean chemistry changes over time.

🌊 Moored Buoys

Floating instruments anchored in key locations provide real-time pH data, helping scientists track rapid changes in ocean chemistry.

Future Predictions and Implications

Based on current trends and climate models, scientists can predict how ocean pH will continue to change in the coming decades.

Projected Changes

If current CO₂ emission trends continue, ocean pH could drop by another 0.3-0.4 units by 2100. This would represent a total change of 150% in ocean acidity since pre-industrial times.

Tipping Points

Some marine ecosystems may reach critical thresholds where they can no longer function normally, leading to collapse of local food webs.

🌎 Global Impact

Changes in ocean chemistry could affect global weather patterns, fish populations that billions of people depend on for food and coastal protection from coral reefs.

Hope for the Future

While ocean acidification is a serious challenge, understanding the problem is the first step towards solutions. Some marine organisms are showing signs of adaptation and reducing CO₂ emissions can slow the rate of change, giving ecosystems more time to adjust.

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